贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响

运用电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、带能谱仪的扫描电镜(SEM-EDX)、逐级化学提取(SCEP)和光学显微镜等方法,对贵州大方煤田11号煤层的地球化学和矿物学进行了研究。结果表明,大方煤田11号煤层中有高含量的脉状石英(11.4%)和脉状铁白云石(10.2%),铁白云石周边常被针铁矿所包裹,在脉状石英中发现有热液成因的黄铜矿、闪锌矿和硒方铅矿,此外,还有少量高岭石充填在脉中,这7种矿物常常同脉共存。脉状石英和脉状铁白云石分别来源于硅质和富铁的钙质低温热液流体,形成温度分别为180℃和85℃。脉状石英早于脉状铁白云石形成。根据Ca/Sr和Fe/Mn值,确定出铁白云石的形成至少经历了3个时期。这7种矿物按照从早到晚的生成顺序为硫化物、石英、高岭石、铁白云石和针铁矿。铁白云石是煤中Mn、Cu、Ni、Pb和Zn富集的主要原因,这5种微量元素的含量分别为0.09%、74.0μg/g、33.6μg/g、185μg/g和289μg/g。脉状石英是煤中铂族元素Pd、Pt和Ir的主要载体,它们在煤中的含量分别为1.57μg/g、0.15μg/g和0.007μg/g。另外,黄铜矿、闪锌矿和硒方铅矿亦是11号煤层中Cu、Zn和Pb的重要载体。     

土壤环境中化学定时炸弹的研究现状与展望

土壤环境中的化学定时炸弹对生态环境乃至人类自身危害极大,国内外均有大规模发生化学定时炸弹的实例,但是,由于其不易发现而常常被忽略,这将造成更为严重的后果。化学定时炸弹的分类问题比较复杂,目前较为妥当的做法是对各种分类方案进行有益的探索。化学定时炸弹的触爆机制研究十分重要,是进行地球化学灾害评价、预测和防治的基础;地球化学工程技术是将来预防和治理化学定时炸弹最主要手段。从科学的严密性和严肃性考虑,化学定时炸弹的概念应该由具有更深刻内涵和更广泛外延的“缓变型地球化学灾害”来替代。     

El Nio事件大气-洋流异常与暖海温传播机理研究

利用1971~2000年逐月SODA(Simple Ocean Data Assimilation)同化资料(Carton等,2004)、1980~2000年逐月NCEP/NCAR再分析资料(Kalnay等,1996)探讨中部型(暖海水首先出现在120°W以西)和东部型(暖海水首先出现在120°W以东)El Nino事件赤道纬向风应力及洋流的异常变化与暖海水信号的传播特征。研究指出:(1)中部型和东部型El Nio事件发生时,太平洋上赤道海表最大西风应力距平在西太平洋地区都有显著的东传现象,但中部型El Nio事件西风应力距平强度强,造成西太平洋赤道表层的东向流可达东太平洋地区,这类El Nio事件强度偏强。(2)中部型El Nio事件,赤道表层洋流辐合区及其下沉运动由西太平洋向东太平洋传播,辐合下沉运动抑制了深层冷海水上翻,西太平洋暖水能够传到东太平洋与西太平洋赤道表层洋流辐合区及其下沉运动的东移有关。(3)东部型El Nio事件西太平洋赤道表层洋流辐合区及其下沉运动没能直接传到东太平洋地区,东太平洋暖水形成与局地(120°W以东)辐合下沉运动抑制深层冷海水上翻有关;东部型El Nio事件暖池次表层的暖水,不是沿着西太平洋赤道次表层向东传播到东太平洋地区,而是由南太平洋西边界流将暖池海水带到40°S左右的西风漂流区,再由西风漂流平流到东太平洋。     

陕西凤县八方山-二里河（铜）铅锌矿床地质特征及成矿模式

在综合分析凤-太矿集区成矿构造特征的基础上，依据以往总结的凤．太矿田铅锌、金矿聚矿构造模式，通过对八方山-二里河铅锌矿床地质特征的分析，总结了找矿标志，初步认为八方山-二里河（铜）铅锌矿床的成矿模式为：“前泥盆纪海底热水喷流沉积一印支-燕山期构造改造型”铅锌矿床。认为成矿物质来源于基底，后期的构造-岩浆改造使基底成矿元素活化，沿同生断裂迁移、改造，最后在泥盆系中形成的扩容性构造部位富集成矿。提出了下一步扩大找矿的方向和建议。     

Structure Refinement of Cs-rich Na-Li Beryl and Analysis of Its Typomorphic Characteristics of Configurations

1 Introduction Natural beryl is an accessory mineral mainly in pegmatite, partly in some highly diffractionated granite or metamorphic rocks, with the crystal shapes beingprismatic, or occasionally tabular. For tabular beryl found in pegmatite it is believed that the tabular configuration is connected with alkali metals (Bieus, 1960; Wang et al., 1981) and geneses of the tabular configuration have been reported before. In recent years, tabular beryl has been found in the Xuebaoding W-Sn-Be d…     

Organic Carbon Isotopic Evolution during the Ediacaran-Cambrian Transition Interval in Eastern Guizhou, South China： Paleoenvironmental and Stratigraphic Implications

Secular variations of carbon isotopic composition of organic carbon can be used in the study of global environmental variation, the carbon cycle, stratigraphic delimitation, and biological evolution, etc. Organic carbon isotopic analysis of the Nangao and Zhalagou sections in eastern Guizhou reveals a negative excursion near the Precambrian-Cambrian boundary that correlates with a distinct carbonate carbon isotopic negative excursion at this boundary globally. Our results also demonstrate that several alternating positive and negative shifts occur in the Meishucunian, and an obvious negative anomaly appears at the boundary between the Meishucunian and Qiongzhusian. The isotope values are stable in the middle and lower parts but became more positive in the upper part of the Qiongzhusian. Evolution of organic carbon isotopes from the two sections in the deepwater facies can be well correlated with that of the carbonate carbon isotopes from the section in the shallow water facies. Integrated with other stratigraphic tools, we can precisely establish a lower Cambrian stratigraphic framework from shallow shelf to deep basin of the Yangtze Platform.     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

Isotope Method for Confined Groundwater Recharge of the Lower Reaches of the Heihe River, Inner Mongolia, China

Environmental isotopes have been applied to analyze confined groundwater recharge in the lower reaches of the Heihe River,Inner Mongolia.CFC is regarded as a tracer that determines the date of groundwater,the date being less than 45 a.The confined groundwater within the Gurinai area and Ejin Basin other than the surface water of Heihe River might have originated from precipitation from Qilian Mountain or/and the Tibetan Plateau.The deep confined groundwater overflows into an upper aquifer and emerges into the ground,forming springs and lakes within the low-lying area.The recharge volume is estimated to be around 400 million-cubic meters.     

Evolution of the Mesozoic Granites in the Xiong''ershan-Waifangshan Region,Western Henan Province,China,and Its Tectonic Implications

Based on the new data of isotopic ages and geochemical analyses, three types of Mesozoic granites have been identified for the Xiong'ershan-Waifangshan region in western Henan Province: high-Ba-SrⅠ-type granite emplaced in the early stage (～160 Ma),Ⅰ-type granite in the middle stage (～130 Ma) and anorogenic A-type granite in the late stage (～115 Ma). Geochemical characteristics of the high-Ba-SrⅠ-type granite suggest that it may have been generated from the thickened lower crust by partial melting with primary residues of amphibole and garnet. Gradual increase of negative Eu anomaly and Sr content variations reflect progressive shallowing of the source regions of these granites from the early to late stage. New 40Ar/39Ar plateau ages of the early-stage Wuzhangshan granite (156.0±1.1 Ma, amphibole) and middle-stage Heyu granite (131.8±0.7 Ma, biotite) are indistinguishable from their SHRIMP U-Pb ages previous published, indicating a rapid uplift and erosion in this region. The representative anorogenic A-type granite, Taishanmiao pluton, was emplaced at～115 Ma. The evolution of the granites in this region reveals a tectonic regime change from post-collisional to anorogenic between～160 Ma and～115 Ma. The genesis of the early- and middle-stageⅠ-type granites could be linked to delamination of subducted lithosphere of the Qiniing orogenic belt, while the late-stage A-type granites represent the onset of extension and the end of orogenic process. In fact, along the Qiniing -Dabie-Sulu belt, the Mesozoic granitoids in western Henan, Dabieshan and Jiaodong regions are comparable on the basis of these temporal evolutionary stages and their initial 87Sr/86Sr ratios, which may suggest a similar geodynamic process related to the collision between the North China and Yangtze cratons.     

对地勘单位贯彻ISO9000《质量管理和质量保证》系列标准的几点认识

ISO9000系列标准是一套国际统一的质量管理标准,应用的主体内容是质量管理模式(质量体系)的建立与运行。其对地勘单位走向市场,到社会投标、承揽地勘项目,保证地勘工作成果质量,提高单位在地质市场中的信誉度具有十分重要的意义。